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Publications |
XRD-support
F. Li, K.
Bravo-Rodriguez, M. Fernandez-Oliva, J. Ramirez-Anguita, K.
Merz, M. Winter, C. W. Lehmann, W. Sander, E.
Sanchez-Garcia Stereochemistry Rules: A Single Stereocenter
Changes the Conformation of a Cyclic Tetrapeptide Journal
of Physical Chemistry B (2013), 117, 10785.
M. Patra, K. Merz,
N. Metzler-Nolte Planar chiral (arene)Cr(CO)3 containing
carboxylic acid derivatives: Synthesis and use in the
preparation of organometallic analogs of the antibiotic
platensimycin Dalton Transactions 41 (2012) 112.
G. Gasser, A.
Pinto, S. Neumann, A. M. Sosniak, M. Seitz, K. Merz, R.
Heumann, N. Metzler-Nolte Synthesis, characterisation and
bioimaging of a fluorescent rhenium-containing PNA
bioconjugate Dalton Transactions 41 (2012) 2304.
M. Patra, G.
Gasser, M. Wenzel, K. Merz, J. Bandow, N.
Metzler-Nolte Sandwich and Half-Sandwich Derivatives of
Platensimycin: Synthesis and Biological
Evaluation Organometallics 31 (2012) 5760.
S. D. Koester, H.
Alborzinia, S. Can, I. Kitanovic, S. Woelfl, R. Rubbiani, I.
Ott, P. Riesterer, A. Prokop, K. Merz, Klaus, N.
Metzler-Nolte A spontaneous gold(i)-azide alkyne
cycloaddition reaction yields gold-peptide bioconjugates which
overcome cisplatin resistance in a p53-mutant cancer cell
line Chemical Science 3 (2012) 2062.
M. Kanthak,
A. Aniol, M. Nestola, K. Merz, I. Oppel, G. Dyker,
Chelated Ruthenium Complexes of Functionalized
Pentaarylcyclopentadienes Organometallics 30 (2011)
215.
S. Nawaz, A. Isab,
K. Merz, V. Vasylyeva, N. Metzler-Nolte, M. Saleem, S. Ahmad,
Saeed Synthesis, characterization and antimicrobial studies
of mixed ligand silver(I) complexes of triphenylphosphine and
heterocyclic thiones: Crystal structure of
bis[{(μ2-diazinane-2-thione)(diazinane-2-thione)(triphenylphosphine)silver(I)
nitrate}] Polyhedron 30 (2011) 1502.
M. Patra, G.
Gasser, M. Wenzel, K. Merz, J. Bandow, N.
Metzler-Nolte Synthesis of Optically Active
Ferrocene-Containing Platensimycin Derivatives with a C6-C7
Substitution Pattern European Journal of Inorganic
Chemistry 2011 (2011) 3295.
J. Zagermann, K.
Klein, K. Merz, M. Molon, N. Metzler-Nolte MOCVD of ZrO2
and HfO2 thin films from modified monomeric precursors
European Journal of Inorganic Chemistry 2011 (2011)
4212.
M. R. Malik, V.
Vasylyeva, K. Merz, N. Metzler-Nolte, M. Saleem, A. Muhammad
I. Saqib; A. Anvarhusein K. Munawar, S. Synthesis, crystal
structures, antimicrobial properties and enzyme inhibition
studies of zinc(II) complexes of thiones Inorganica Chimica
Acta 376 (2011) 207. M. Patra, G. Gasser, M.
Wenzel, K. Merz, J. E. Bandow, N. Metzler-Nolte Synthesis
and Biological Evaluation of Ferrocene-Containing
Bioorganometallics Inspired by the Antibiotic Platensimycin
Lead Structure Organometallics 29 (2010)
4312.
M. Patra, G.
Gasser, D. Bobukhov, K. Merz, A. V. Shtemenko, N.
Metzler-Nolte Sequential insertion of three different
organometallics into a versatile building block containing a
PNA backbone Dalton Transactions 39 (2010) 5617.
K. Splith, I.
Neundorf, W. Hu, H. W. P. N'Dongo, V. Vasylyeva, K. Merz, U.
Schatzschneider Influence of the metal complex-to-peptide
linker on the synthesis and properties of bioactive CpMn(CO)3
peptide conjugates Dalton Transactions 39 (2010)
2536.
P. Nockemann, K.
Binnemans, B. Thijs, T. N. Parac-Vogt, K. Merz, A.-V. Mudring,
P. C. Menon, R. N. Rajesh, G. Cordoyiannis, J. Thoen, J. Leys,
C. Glorieux Temperature-Driven Mixing-Demixing
Behavior of Binary Mixtures of the Ionic Liquid Choline
Bis(trifluoromethylsulfonyl)imide and Water. Journal of
Physical Chemistry 113(5) (2009) 1429.
M. Mastalerz, I.
Oppel, K. Merz, G. Dyker Tetrapyridoxycalix[4]arene and its
copper(II) complex: An ionic crystal engineering tecton for
self-inclusion polymers. Journal of Inclusion Phenomena and
Macrocyclic Chemistry 64(1-2) (2009) 157.
J. Zagermann, M.
Kuchta, K. Merz, N. Metzler-Nolte Ruthenium-based
bioconjugates: Synthesis and X-ray structure of the mixed
ligand sandwich compound RuCpiPr(p-(CO2H)C6H4Tp) and labeling
of amino acids and the neuropeptide enkephalin. Journal of
Organometallic Chemistry 694(6) (2009) 862.
S. Boichut, C.
Boyer, K. Burger, A. Haas, K. Merz, T. Pages, T. Wallmichrath
2-Methyl-6,6-bis(trifluoromethyl)cyclohex-3-ene-1-carbaldehyde:
Reactivity and application as a model for the preparation of
16,16,16,17,17,17,-hexafluororetinal analogs J. Organic and
Pharmaceutical Chemistry 1(21) (2008) 3.
R. Pietschnig, S.
Spirk, G. N. Rechberger, K. Merz Selenenylphosphonium ions
as intermediates in the phosphane assisted methylation of
elemental selenium. Inorganica Chimica Acta 361(7) (2008)
1958.
J. Niesel, A.
Pinto, H. W. Peindy N'Dongo, K. Merz, I. Ott, R. Gust, U.
Schatzschneider Photoinduced CO release, cellular uptake
and cytotoxicity of a tris(pyrazolyl)methane (tpm) manganese
tricarbonyl complex. Chem.Commun. (2008) 1798.
S. Yao, M. Brym,
K.Merz, M. Driess Facile Access to a Stable Divalent
Germanium Compound with a Terminal PH2 Group and Related PR2
Derivatives. Organometallics 27(14) (2008)
3601.
N. Dona, K. Merz,
M. Driess Novel dimeric pentacoordinate silicon complexes:
unusual reactivity of electron-rich aminosilane intermediates.
Organosilicon Chemistry VI: From Molecules to Materials
(2008) 271.
M. Mastalerz, H. J.
E, Rivera, W. Hueggenberg, K. Merz, I. Oppel, G. Dyker
Pyridoxycalix[4]arene palladium(II) complexes as tectons
for self-inclusion polymers. CrystEngComm 10(9)
(2008) 1120.
X. de Hatten, E.
Bothe, K. Merz, I. Huc, N. Metzler-Nolte A
ferrocene-peptide conjugate as a hydrogenase model system.
European Journal of Inorganic Chemistry 29 (2008)
4530.
H. W. P. N'Dongo,
I. Neundorf, K. Merz, U. Schatzschneider Synthesis,
characterization, X-ray crystallography, and cytotoxicity of a
cymantrene keto carboxylic acid for IR labelling of bioactive
peptides on a solid support.
Journal of Inorganic Biochemistry 102(12) (2008)
2114.
I.K. Srecko, T.
Weyhermüller, K. Merz, N. Metzler-Nolte The X-Ray Single
Structures of a Carboxylato-subtituted Bis(2-picolyl)amine
(bpa) Ligand with Pd(II) and Zn(II) display different
intermolecular interactions around the common (H2O)2(anion)2
motif Z. Anorg. Allg. Chem. 633 (2007) 2706.
G. Dyker, K. Merz,
I. M. Oppel, E. Muth Palladium-Catalyzed Naphthylation of
Acenaphthylene Synlett 6 (2007) 897.
A. Milanov, R.
Thomas, M. Hellwig, R. Bhakta, K. Merz, H.-W. Becker, P.
Ehrhart, R. A. Fischer, R. Waser, and A. Devi LI-MOCVD of
HfO2 thin films using engineered amide based Hf precursors
Surface and Coatings Technology 201 (2007)
9109.
R. Pietschnig, K.
Merz
Self organization of organo fluorosilicates in the
nanometer range. Proceedings of ECSOC-9, International
Electronic Conference on Synthetic Organic Chemistry, 9th,
Nov. 1-30 (2005) F002/1.
D. Kadzimirsz, D.
Hildebrandt, K. Merz, G. Dyker Isoindoles and
dihydroisoquinolines by gold-catalyzed intramolecular
hydroamination of alkynes Chem. Commun. (2006)
661.
M. Gonschorowsky,
K. Merz, M. Driess Cyclohexylbis(hydroxymethyl)phosphane:
a hydrophilic phosphane capable of forming novel
hydrogen-bonding networks Eur. J. Inorg. Chem. (2006)
455.
J. Liu, E. Muth, U.
Flörke, G. Henkel, K. Merz, J. Sauvageau, E. Schwake, G. Dyker
Alkylation of arenes with benzylic and propargylic
alcohols - classical versus fancy catalysts Advanced
Synthesis & Catalysis 384 (2006) 456.
U. Patil, R.
Thomas, A. Milanov, R. Bhakta, P. Ehrhart, R. Waser, R.
Becker, H.-W. Becker, M. Winter, K. Merz, R. A. Fischer, A.
Devi MOCVD of ZrO2 and HfO2 thin films from modified
monomeric precursors Chemical Vapor Deposition 12(2-3)
(2006) 172.
M. Mastalerz, G.
Dyker, U. Floerke, G. Henkel, I. Oppel, K. Merz
Oligophenylcalix[4]arenes as potential precursors for
funnelenes and calix[4]triphenylenes: syntheses and
preliminary cyclodehydration studies. European Journal of
Organic Chemistry 21 (2006) 4951.
C. Tönshoff, K.
Merz, G.
Bucher
Azidocryptands-synthesis, structure, and complexation
properties Org. Biomol. Chem. 3 (2005) 303. R.
Pietschnig, K.
Merz
Fluoro-bis-iso-propyl-(2,4,6-tris-iso-propylphenyl)silane,
i-Pr2(2,4,6-i-Pr3C6H2)SiF Appl. Organomet. Chem. 19 (2005)
206. M. Driess, J. Aust, K.
Merz
From dinuclear zirconium(+3)-phosphido complexes
{[Cp2ZrP(H)R]2} to the first neutral
zirconocene-phosphinidene dimers [(Cp2ZrPR)2] by P-H
dehydrogenation Eur. J. Inorg. Chem. (2005)
866. R. Pietschnig, K. Merz, S.
Schäfer
Synthesis, charge distribution, and dimerization behavior
of lithium alkynylselenolates Heteroatom Chem. 16 (2005)
169. A.P. Milanov, R. Bhakta, M. Winter, K. Merz,
A.
Devi
Bis(2-butyl-N,N'-diisopropylamidinato)dichlorohafnium(IV) Acta
Cryst. C 61 (2005) m370. R. Pietschnig, S. Spirk,
F. Belaj, K.
Merz
Synthesis and structure of a 2,4-unsubstituted
cis/trans-1,3-disilacyclobutane by dehydrofluorination of a
highly hindered fluorosilane Eur. J. Inorg. Chem. (2005)
2151. M. Driess, N. Muresan, K. Merz, M.
Päch
Formation of a bowl-shaped, pentacyclic phosphonium cage
by methylation of a nucleophilic phosphinidene Angew.
Chem. Int. Ed. 44 (2005) 6734. M. Driess, N.
Muresan, K.
Merz
A novel type of pentacoordinate silicon complexes and
unusual ligand coupling by intramolecular electron
transfer Angew. Chem. Int. Ed. 44 (2005) 6738.
G. Dyker, M. Mastalerz, I. Müller, K. Merz, K.
Koppe
Solvent-dependent pseudopolymorphism of
tripyridoxycalix[4]arene: Cone versus partial-cone
conformation Eur. J. Org. Chem. (2005)
4963. R. Pietschnig, K.
Merz
Selective Formation of Functionalized Disiloxanes from
Terphenylfluorosilanes Organometallics 23 (2004)
1373. M. Driess, N. Dona, K.
Merz
Metal-induced formation of a new chiral bidentate N,O
ligand and the synthesis of novel monomeric
germylenes Dalton Trans. (2004) 3176. M.
Driess, N. Dona, K.
Merz
Novel hypervalent complexes of main-group metals by
intramolecular ligand-to-metal electron transfer J.
Chem. Eur. 10 (2004) 5971.
R. Pietschnig, S.
Schäfer, K.
Merz
Self-Addition of a Sterically Hindered
Alkynylselenolate Org. Lett. 5 (2003) 1867. M.
Driess, K. Merz, C.
Monse
Synthesis of the first fluoro(phosphanyl)-
and diphosphanyl-stannanes and surprising formation of
[P(SnMe3)4]+SiF5- Chemical Communications (2003)
2608. G. Dyker, D. Hildebrandt, J. Liu, K.
Merz
Gold(III) chloride catalyzed domino processes
with isobenzopyrylium cation intermediates Angew. Chem.
Int. Ed. 42(36) (2003) 4399. E.M. Coyanis, C.O.
Della Vedova, A. Haas, K.
Merz
Synthesis and characterization of trifluoromethyl
heterocyclic compounds:
4-hydroxy-4-methyl-5-(2,2,2-trifluoro-1-trifluoro methylethyl)-1,3-thiazoline
derivatives J. Mol. Struct. 660 (2003) 147. M.
Cokoja, T. Steinke, C. Gemel, T. Welzel, M. Winter, K.
Merz,
R.A. Fischer Ligand properties of CpGa: new examples of
Mo-Ga and W-Ga complexes Journal of Organometallic
Chemistry 684 (2003) 277. G. Dyker, M. Mastalerz,
K.
Merz
From a calix[4]arene to a hexameric
supracycle. European Journal of Organic Chemistry 22 (2003)
4355. M. Driess, H. Ackermann, J. Aust, K. Merz,
C. von
Wüllen
As[P(NMe2)3]2+ als simultane AsI- und PI-Quelle: Synthese
und Dichtefunktionalrechnungen planar-tetrakoordinerter
Arsonium- und Phosphoniumionen Angew. Chem. 114 (2002)
467. H. Ackermann, J. Aust, M. Driess, K. Merz,
C. Monse, C. v.
Wüllen
How to tame planar and main group metal-substituted onium
ions of phosphorus and arsenic Phosphorus, Sulfur and
Silicon 177 (2002) 1613. Q. Cheng, O. Stark, K.
Merz, M. Winter, R.A.
Fischer
Lewis base properties of Tris(trimethylstannyl)amine:
unusually short M-N bonds of the adduct compounds
[X3MN(SnMe3)3] (X = Cl, Br; M = Al, Ga, In) and
[Cl2(CH3)MN(SnMe3)3] (M = Al, Ga) Dalton Trans. (2002)
2933. R. Boese, A. Haas, E. Hoppmann, K. Merz, A.
Olteanu
Preparation of acylic and heterocyclic
tellurathianitrogen compounds:Contribution to a better
understanding of complex reaction pathways Z. Anorg.
Allg. Chem. 628 (2002) 673. D. Weiss, M. Winter,
K. Merz, A. Knüfer, R.A.
Fischer,
N. Fröhlich, G. Frenking Synthesis, structure and
bonding situation of [(dpce)Pt(InCp*)2] and
{(dpce)Pt[GaC(SiMe3)3]2} - two novel examples of
platinum complexes of low valent Group 13 metal
species Polyhedron 21 (2002) 535. R. Weiss, F.
Pühlhofer, N. Jux, K.
Merz
Massive sterische und elektrostatische Stäkrung des
Porphyrinsystems: Einstufige Synthese eines
diskretenorganisch-anorganischen Inonenclusters auf
Porphyrinbasis durch eine
Polyonio-substitutionskaskade Angew. Chem. 114 (2002)
3969. M. Driess, J. Aust, K.
Merz
P-H-Activation Through Amido Zirconium Complexes: From
new Phosphanido Zir-conium Complexes To the First
Zr2P6-Cluster With an [RP-P-PR]3- -Ligand Eur. J. Inorg.
Chem. (2002) 2961. M. Driess, F. Franke, K.
Merz
Facile synthesis and ambident coordination
ofcyclohexylbis-(2-pyridyl)- phosphane: novel dinuclear
complexes of Cu+1, Ag+1, and Co+2 ions Eur. J. Inorg. Chem.
10 (2001) 2661. A. Haas, E. Hoppmann, K.
Merz
Bis(sulfinylamido)tellurium(IV)fluoride: a versatile
synthon in tellurium-nitrogen chemistry J. Fluorine
Chem. 112 (2001) 197. R. Becker, J. Weiss, M.
Winter, K. Merz, R.A.
Fischer
New heterometallic copper zinc alkoxides: synthesis,
structure properties and pyrolysis to Cu/ZnO
composites J. Organomet. Chem. 630(2) (2001)
253. N. Oberbeckmann, K. Merz, R.A.
Fischer
Coordination of Donor-Functionalized Cyclopentadienyl
Ligands at Platinum(II) Centers: Syntheses and Molecular
Structure
of [(1,2-:5,6-cod){(C5Me4CH2CH2NMe2)MePt}2] Organometallics
20 (2001) 3265. M. Driess, R. Barmeyer, C. Monse,
K.
Merz
E(SiMe3)4+ ions (E = P, As): persilylated phosphonium and
arsonium ions Angew. Chem., Int. Ed. 40(12) (2001)
2308. J. Dworak, A. Haas, E. Hoppmann, A.
Olteanu, K. Merz, M.
Schäfers
Preparation of Tellurium-Nitrogen containing Moities in
Ionic Chainmolecules,Heterocycles as well as (CF3Se)2Te,
/CF3S)2Se, and (CH3)2Te(X)Y(X = Y = NCO, NSO; X = Cl, Y =
NSO) Z. Anorg. Allg. Chem. 627 (2001) 2639. R.
Pietschnig, K.
Merz
The first polymer with a fluorosilicate backbone and a
non-polar shell Chem. Commun. 13 (2001)
1210. M. Driess, C. Monse, K.
Merz
Tetraphosphinosilane-a mild PH2-transfer reagent and
building block for the synthesis of a rhombododecahedral
Li6P6Si2-cluster framework Z. Anorg. Allg. Chem. 627 (2001)
1225. M. Driess, K. Merz, R.B.
Rowlings
Orthotelluric acid as substitute for crystal-water:
syntheses and crystal structure of the Co-crystallate
[Te(OH)6·2adenine·4H2O] and the disodium ditellurate(VI)
aggregate {[Te2O2(OH)6(ONa)2]2[NaOH·12.5 H2O]} Z.
Anorg. Allg. Chem. 627 (2001) 213. H.
Braunschweig, M. Colling, C. Kollann, K. Merz, K.
Radacki
[(OC)5Cr=B-Si(SiMe3)3]: A Terminal Borylene Complex with
an Electronically Unsaturated at Boron Atom Angew. Chem.
113 (2001) 4327. M. Driess, K. Merz, S.
Rell
Synthesis and structure of siloxy-substituted ZnO
aggregates having (ZnO)n (n = 2, 4) and Zn3O4 cores Eur.
J. Inorg. Chem. 12 (2000) 2517. M. Driess, K.
Merz, C.
Monse
P(SiiPr3)3: the first trisilylphosphine derivative with an
almost planar three-coordinated phosphorus atom Z.
Anorg. Allg. Chem. 626 (2000) 2264. M. Driess, C.
Monse, K. Merz, C. van
Wüllen
Perstannylated ammonium and phosphonium ions:
organometallic onium ions that are also base-stabilized
stannylium ions Angew. Chem., Int. Ed. 39(20) (2000)
3684. H. Fölsing, O. Segnitz, U. Bossek, K. Merz,
M. Winter, R.A.
Fischer
Synthesis and structure of adduct stabilized Group IIIA
metal transition metal carbonyl complexes: new examples for
Fe-Ga, Fe-In, W-Al, Cr-Al and Cr-Ga bonds J. Organomet.
Chem. 606(2) (2000) 132. O. Segnitz, M. Winter,
K. Merz, R.A.
Fischer
The hemilabile [2-(dimethylamino)ethyl]cyclopentadienyl
ligand and nickel: preparation and structural analysis of
new cationic and neutral complexes Eur. J. Inorg. Chem. 9
(2000) 2077.
M. Driess, C. v.
Hänisch, K.
Merz
The First Orthotelluric Acid Polysiyl Esters: Synthesis
and Crystal Structure of [(Me3SiO)8Te2O2] and
[(Me4Si2O2)3Te] Z. Anorg. Allg. Chem. 625 (1999)
1. K. Brandt, A. Haas, T. Hardt, H. Mayer-Figge,
K. Merz, T.
Wallmichrath
Synthesis of Geminal-Bis(trifluoromethyl)-substituted
Dienes, Hetrodienes, 7,7,7,8,8,8 Hexafluoro-cyclocitral and
-sefranal J. Fluorine Chem. 97 (1999) 115. M.
Driess, U. Hoffmanns, S. Martin, K. Merz, H.
Pritzkow
Lithiated Clusters from Primary Silylphosphanes and
Silylarsanes: Spherical Bodies with and without Li2O
Filling Angew. Chem. Int. Ed. 38 (1999)
2733. Driess, S. Rell, K.
Merz
Ungewöhnliche Reaktivität der
Silicium-Phosphor-Doppelbindung in einem
Silyliden(fluorsilyl)phosphan: intramolekulare
C,H-Inserierung und seine Umwandlung in ein neues
Silyliden(silyl)phoshan Z. Anorg. Allg. Chem. 625 (1999)
1119. M. Driess, J. Aust, K. Merz, H.
Pritzkow
From New Zirconium-Phosphanide to Phosphinidene
Complexes Phosphorus, Sulfur and Silicon 147 (1999)
841. M. Driess, M. Faulhaber, K.
Merz
Synthese eines gemischt-metallierten
Dilithiumdisilber-Cyclosila- phosphanid Komplexes mit
anziehenden AgI-AgI-Wechselwikungen Z. Anorg. Allg. Chem.
625 (1999) 2192. M. Driess, J. Aust, K. Merz, C.
v.
Wüllen
van´t Hoff-Le Bel Stranger: Formation of a Phosphonium
Cation with a Planar Tetracoordinate Phosphorus
Atom Angew. Chem. Int. Ed. 38 (1999) 3677. M.
Häusslein, H.-D. Hausen, K. W. Klinkhammer, J. Weidlein, K.
Merz
Synthese, Spektren und Strukturen einfacher Derivate
des Tris(bis(trimethylsilyl)methyl)indiums,
In(CH(Si(CH3)3)2)3 Z. Anorg. Allg. Chem. 625 (1999)
1608. M. Driess, F. Faulhaber, K.
Merz
Synthesis and molecular structure of the first
tetranuclear copper(I) silylphosphido cluster
[Cu(CyPSiMe2PHCy)] Chem. Comm. (1998) 1887.
M. Driess, S.
Martin, K. Merz, H. Pritzkow, V.
Pintchouk,
H. Grützmacher, M.Kaupp [Sn6(PR)6], [Sn3(PR)2Cl2] und
[Cu24(PR)12] (R = Triorganosilyl): Neue Zinn- und
Kupfer-Phosphandiylcluster Angew. Chem. 109 (1997)
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